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Stereochemical course of the formation of the C(7)-formyl group from a chiral methyl group during the transformation of chlorophyllide a into chlorophyllide b

Stereochemical course of the formation of the C(7)-formyl group from a chiral methyl group during the transformation of chlorophyllide a into chlorophyllide b
Stereochemical course of the formation of the C(7)-formyl group from a chiral methyl group during the transformation of chlorophyllide a into chlorophyllide b
The biosynthesis of chlorophyll a and chlorophyll b from (2R,3R)- and (2S,3S)-5-amino[2,3-14C2,2,3- 2H2,2,3-3H2]levulinic acid in greening barley has established that chlorophyllide a oxidase catalyses the transformation of the methyl group at C(7) of chlorophyllide a into the CHO group of chlorophyllide b with the loss of HSi from the 7-(hydroxymethyl)chlorophyllide intermediate.
0018-019X
4185-4194
Shoolingin-Jordan, Peter M.
ac0bf2cc-ee36-4b30-bcef-525cee2559f7
Williams, Stephen C.
4ba2e0a2-8c24-4cc0-a14b-cd5f15d5ec3f
Shoolingin-Jordan, Peter M.
ac0bf2cc-ee36-4b30-bcef-525cee2559f7
Williams, Stephen C.
4ba2e0a2-8c24-4cc0-a14b-cd5f15d5ec3f

Shoolingin-Jordan, Peter M. and Williams, Stephen C. (2003) Stereochemical course of the formation of the C(7)-formyl group from a chiral methyl group during the transformation of chlorophyllide a into chlorophyllide b. Helvetica Chimica Acta, 86 (12), 4185-4194. (doi:10.1002/hlca.200390344).

Record type: Article

Abstract

The biosynthesis of chlorophyll a and chlorophyll b from (2R,3R)- and (2S,3S)-5-amino[2,3-14C2,2,3- 2H2,2,3-3H2]levulinic acid in greening barley has established that chlorophyllide a oxidase catalyses the transformation of the methyl group at C(7) of chlorophyllide a into the CHO group of chlorophyllide b with the loss of HSi from the 7-(hydroxymethyl)chlorophyllide intermediate.

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Published date: December 2003
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Identifiers

Local EPrints ID: 26765
URI: http://eprints.soton.ac.uk/id/eprint/26765
DOI: doi:10.1002/hlca.200390344
ISSN: 0018-019X
PURE UUID: 37c4835e-176f-4db2-a4b2-a1ed28e91dce

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Date deposited: 11 Apr 2006
Last modified: 15 Mar 2024 07:13

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Contributors

Author: Peter M. Shoolingin-Jordan
Author: Stephen C. Williams

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