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Unveiling the redox-active character of imidazolin-2-thiones derived from amino-substituted N-heterocyclic carbenes

Abstract

International audienceIMes-derived thioureas in which the imidazolyl ring is directly substituted by one or two dimethylamino groups are redox-active, exhibiting one and two oxidized states, respectively. The structure, stability, and electronics of the oxidized species are investigated, emphasizing the decisive role of the amino substituents

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Hal - Université Grenoble Alpes

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Last time updated on 07/01/2019

This paper was published in Hal - Université Grenoble Alpes.

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