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oaioai:casi.ntrs.nasa.gov:20080012244

Photochemical preparation of olefin addition catalysts

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1978
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Abstract

Novel polymer supported catalysts are prepared by photo-irradiation of low valent transition metal compounds such as Co.sub.2 (CO).sub.8, Rh.sub.4 (CO).sub.12 or Ru.sub.3 (CO).sub.12 in the presence of solid polymers containing amine ligands such as polyvinyl pyridine. Hydroformylation of olefins to aldehydes at ambient conditions has been demonstrated

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This paper was published in NASA Technical Reports Server.

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