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oaioai:depositonce.tu-berlin.de:11303/6888

Stereoselective alkyne semihydrogenations with an air-stable copper(I) catalyst

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Publication date
1 January 2016
Publisher
Doi

    Abstract

    An air-stable and preactivated copper(I) hydroxide/N-heteroyclic carbene (NHC) complex for alkyne semihydrogenations is reported. Next to an enhanced practicability of the process, the resulting alkenes are obtained with high Z-selectivities and no overreduction to the corresponding alkanes

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