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Synthesis of Five‑, Six‑, and Seven-Membered 1,3- and 1,4-Heterocyclic Compounds via Intramolecular Hydroalkoxylation/Hydrothioalkoxylation of Alkenols/Thioalkenols
Abstract
Intramolecular hydroalkoxylation/hydrothioalkoxylation of nitrogen-tethered alkenes and alcohols/thiols mediated by boron trifluoride etherate leads to five-membered thiazolidine, six-membered 1,4-oxazines (morpholines) and tetrahydro-2<i>H</i>-1,4-thiazines (thiomorpholines), and seven-membered 1,4-oxazepanes in good yields- Text
- Journal contribution
- Biochemistry
- Genetics
- Pharmacology
- Science Policy
- Mental Health
- Infectious Diseases
- Virology
- Chemical Sciences not elsewhere classified
- hydroalkoxylation
- thiazolidine
- oxazepane
- oxazine
- Compound
- Synthesi
- alkene
- tetrahydro
- Heterocyclic
- thiomorpholine
- Alkenol
- boron trifluoride etherate
- yield
- Hydroalkoxylation
- morpholine
- Intramolecular